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Your Y DNA and mtDNA results are surprises. Below is a list of ancient Ws I'm aware of.
W1c'i: I1097, 6500-6200 BC, Barcin Turkey
W6: Va7, 5500-4500 BC, Romania
W: Starčevo Culture, ~5500 BC, Hungary=2
W1c'i: LBK Culture, ~5000 BC, Germany=2
W: LBK Culuture, ~5000 BC, Germany=1
W1c-i: Schöningen Culture, ~4000 BC, Germany=2
W: QLB 3, ~3800 BC, Germany
W1c'i: BENZ18, ~3000 BC, Germany=1
W: MAJ9, ~3500-3000 BC, Steppe
W6: ~3500-3000 BC, Yamnaya=2
W3a1a: SVP57, ??, Yamnaya
W6a: ESP16, 2600 BC, Corded Ware Germany
W1c1: BZH 15, 2500-2050 BC, Bell Beaker Germany
W: EUL 22, 2198-2162 BC, Bell Beaker Germany
W3a1: ESP4, 2118-1961 BC, Unetice Germany
W: ~2000 BC, Unetice Germany=2
W: 6H, ~2000 BC, Minoan